Incipient Dynamics of Swelling of Gels

نویسندگان

  • Hang Zhang
  • Maria-Carme Calderer
چکیده

In this article, we analyze a model of the incipient dynamics of gel swelling, and perform numerical simulations. The governing system consists of balance laws for a mixture of nonlinear elastic solid and solvent yielding effective equations for the gel. We discuss the multiscale nature of the problem and identify physically realistic regimes. The mixing mechanism is based on the Flory-Huggins energy. We consider the case that the dissipation mechanism is the solid-solvent friction force. This leads to a system of weakly dissipative nonlinear hyperbolic equations. After addressing the Cauchy problem, we propose physically realistic boundary conditions describing the motion of the swelling boundary. We study the linearized version of the free boundary problem. Numerical simulations of solutions are presented too.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Abstract Submitted for the MAR06 Meeting of The American Physical Society Length scale dependent relaxation in colloidal gels EMANUELA

Submitted for the MAR06 Meeting of The American Physical Society Length scale dependent relaxation in colloidal gels EMANUELA DEL GADO, Dipartimento di Scienze Fisiche, Universita’ degli Studi di Napoli “Federico II”, WALTER KOB, Laboratoire des Cooloides, Verres et Nanomateriaux, Universite Montpellier II — Although gels are ubiquitous in fundamental science, technological applications and als...

متن کامل

Electroresponsive Acrylic Gels

This articles is comprised of two parts: a) an experimental investigation on the behavior of an acrylic gel under DC electric field and b) a physico - mathematical description.a) Gel rods made of poly [acrylamide-co-bisacrylamide] were partially hydrolyzed to different extents at pH 12 by teteramethylethylene diamine. Equlibrium properties of the resulting gels rods (water content,...

متن کامل

Equilibrium Swelling Study of Cationic Acrylamide-Based Hydrogels: Effect of Synthesis Parameters, and Phase Transition in Polyelectrolyte Solutions

Cationic copolymer gels of acrylamide and [(methacrylamido) Propyl] trimethyl ammonium chloride (MAPTAC) were synthesized by free radical aqueous solution polymerization. The Taguchi method, a robust experimental design, was employed for the optimization of the synthesis based on the equilibrium swelling capacity of the hydrogels. Based on Taguchi method a standard L16 orthogonal array with fiv...

متن کامل

Oscillatory dynamics induced in polyelectrolyte gels by a non-oscillatory reaction: a model.

We develop a general model and the associated numerical algorithm to compute the swelling dynamics of chemo-responsive polyelectrolyte gels immersed in a reactive ionic solution kept at a non equilibrium stationary state by a permanent feed of fresh reactants. Using an autocatalytic bistable but nonoscillatory reaction, namely, the bromate-sulfite reaction, we predict that a piece of hydrogel t...

متن کامل

Formation and Aging of Incipient Thin Film Wax-Oil Gels

A fundamental study of the deposition and aging of a thin incipient wax-oil gel that is formed during the flow of waxy oils in cooled pipes was performed. The solubility of high molecular weight paraffins in naphthenic, aromatic or paraffinic sol®ents is ®ery low and decreases rapidly with decreasing temperature. This property of the paraffins leads to the formation of gels of complex morpholog...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • SIAM Journal of Applied Mathematics

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2008